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A stereoselective hydride transfer reaction with contributions from attractive dispersion force control.
Braddock, D Christopher; Limpaitoon, Natnicha; Oliwa, Krzysztof; O'Reilly, Daniel; Rzepa, Henry S; White, Andrew J P.
Affiliation
  • Braddock DC; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Limpaitoon N; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Oliwa K; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • O'Reilly D; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Rzepa HS; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • White AJP; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
Chem Commun (Camb) ; 58(32): 4981-4984, 2022 Apr 19.
Article in En | MEDLINE | ID: mdl-35322841
The experimentally determined stereochemical outcome of an unprecedented hydride transfer from a lithium alkoxide to an aldehyde is reported, as deconvoluted by the combined use of a single enantiomer alkoxide in conjunction with a deuterium label. The stereoselective outcome is consistent with a computationally predicted transition state model stabilised by contributions from attractive dispersion forces.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Stereoisomerism Type of study: Prognostic_studies Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Country of publication:
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Stereoisomerism Type of study: Prognostic_studies Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Country of publication: