A stereoselective hydride transfer reaction with contributions from attractive dispersion force control.
Chem Commun (Camb)
; 58(32): 4981-4984, 2022 Apr 19.
Article
in En
| MEDLINE
| ID: mdl-35322841
The experimentally determined stereochemical outcome of an unprecedented hydride transfer from a lithium alkoxide to an aldehyde is reported, as deconvoluted by the combined use of a single enantiomer alkoxide in conjunction with a deuterium label. The stereoselective outcome is consistent with a computationally predicted transition state model stabilised by contributions from attractive dispersion forces.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Stereoisomerism
Type of study:
Prognostic_studies
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2022
Document type:
Article
Country of publication: